Ni supported on mesostructured silica nanoparticles (MSN) and MCM-41 were successfully prepared using an in situ electrochemical method. The N 2 physisorption results indicated that the introduction of Ni altered markedly the surface properties of MCM-41 and MSN.
Pure mesoporous silica nanoparticles were prepared according to published literature procedure. 3 The CTAB surfactant was removed by calcination at 550 °C for 5 h. Attachment of the ICPES linker was accomplished by suspending 100 mg of the calcined particles in 10 mL of a 10 mM solution of ICPES in dry PhMe and refluxing for 12 h under N 2 .
2012-11-15 · In this work, mesostructured silica nanoparticles (MSN(AP)) with high adsorptivity were prepared by a modification with 3-aminopropyl triethoxysilane (APTES) as a pore expander. The performance of the MSN(AP) was tested by the adsorption of MB in a batch system under varying pH (2-11), adsorbent dosage (0.1-0.5 g L(-1)), and initial MB concentration (5-60 mg L(-1)). 2017-07-01 · Core-shell hierarchical mesostructured silica nanoparticles for gene and chemodrug co-delivery in sequence: We have successfully developed a “chemical homology” strategy for the fabrication of core-shell hierarchical mesostructured MSNs (H-MSNs) with different-sized mesopores and composition-varied frameworks separately in the core and shell. Mesoporous silica nanoparticles (MSNs) have garnered a great deal of attention as potential carriers for therapeutic payloads. Here, we report a pH-responsive drug-carrier based on chondroitin sulfate functionalized mesostructured silica nanoparticles (NMChS-MSNs) ie, the amidation between NMChS macromer and amino group functionalized MSNs.
Large pore mesoporous silica nanoparticles (LP-MSNs) functionalized with poly-l-lysine (PLL) were designed as a new carrier material for gene delivery applications. The synthesized LP-MSNs are 100–200 nm in diameter and are composed of cage-like pores organized in a cubic mesostructure. 2015-01-15 · Mesostructured silica nanoparticles (MSN) represent a potential support, which has a high surface area and contains acidic/basic features , , , . These properties can enhance the adsorption of CO 2 onto the support surface. A catalyst containing small (ca. 2.5 nm) and crystalline Pt nanoparticles embedded into the walls of a mesostructured silica framework was found to be highly active in alkene hydrosilylation reaching TONs of ca.
Acidic sulfate and acetate water solution was used for Suzuki, K, Ikari, K, Imai, H. Synthesis of silica nanoparticles having a well-ordered mesostructure using a double surfactant system. J Am Chem Soc 2004; 126: 16 Apr 2015 MSNPs were biocompatible, and particles not retained within the tumors, were degraded and eliminated mainly by renal excretion.
DOI: 10.1021/CM504448U Corpus ID: 102124520. Ultraporous Mesostructured Silica Nanoparticles @article{Egger2015UltraporousMS, title={Ultraporous Mesostructured Silica Nanoparticles}, author={Sam M Egger and Katie R. Hurley and Ashish Datt and Garrett R. Swindlehurst and C. Haynes}, journal={Chemistry of Materials}, year={2015}, volume={27}, pages={3193-3196} }
10 Aug 2016 A series of Ni incorporated Mesostructured Silica Nanoparticles (MSN) were prepared by physical mixing method. Electrolyzed nickel oxide 11 Apr 2014 The mesostructured silica nanoparticles obtained before dialysis were therefore used as the seeds, because the nanoparticles were dissolved substitution route to prepare mesostructured silica nanoparticles loaded with zinc oxide catalyst loaded on mesostructured silica nanoparticles (ZnO/MSN). 29 Dec 2015 Mesoporous Silica Nanoparticles (MSN): A Nanonetwork nanocrystals were encapsulated inside mesostructured silica spheres that were 9 Oct 2012 Chondroitin sulfate functionalized mesostructured silica nanoparticles as biocompatible carriers for drug delivery Juqun Xi,1 Jin Qin,2 Lei 2 Mar 2013 Core–shell nanoparticles consisting of iron oxide (α-Fe2O3) core and mesostructured silica–surfactant composite shell are treated with 9 Jan 2014 siRNA by mesoporous silica nanoparticles enhances the efficacy of functionalized large pore cubic mesostructured silica nanoparticles as 17 Oct 2018 Silica nanoparticles of between 1 – 100 nm in diameter are cost-effective and simple to produce, with a highly modifiable surface chemistry, 15 Aug 2017 et al. Microemulsion templating of siliceous mesostructured cellular foams with well-defined ultralarge mesopores.
Abstract: Mesoporous silica nanoparticles (MSNs) have garnered a great deal of attention as potential carriers for therapeutic payloads. Here, we report a pH-responsive drug-carrier based on chondroitin sulfate functionalized mesostructured silica nanoparticles (NMChS-MSNs) ie, the amidation between NMChS macromer and amino group functionalized
Here, we report a pH-responsive drug-carrier based on chondroitin sulfate functionalized mesostructured silica nanoparticles (NMChS-MSNs) ie, the amidation between NMChS macromer and amino group functionalized and unfunctionalized silica nanoparticles. At a low con-centration (<100 μg/mL), LP-MSN-P has low cytotoxicity. Moreover, we also demonstrate that the LP-MSN-P can effectively deliver siRNA into cancer cells and silence the oncogenes. RESULTS AND DISCUSSION Synthesis of Large Pore Mesoporous Silica Nanoparticles (LP-MSNs). Abstract This study reports an efficient method for the preparation of well-dispersed ruthenium nanoparticles of controlled size loaded into micelle-templated silica (MTS). This method is based on an organometallic approach consisting in mild decomposition of Ru(COD)(COT) (COD = η 4 -cycloocta-1,5-diene; COT = η 6 -cycloocta-1,3,5-triene) embedded inside mesostructured porous silica.
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Controlled, self-assembly of silica nanoparticles into uniform mesostructured or biological species into colloidal suspension of silica (SiO2) nanoparticles. nanoparticles was obtained using octane as a hydrophobic support and styrene mesostructured silica particles, moreover in the reduction of the particle size
9 Oct 2012 Chondroitin sulfate functionalized mesostructured silica nanoparticles as biocompatible carriers for drug delivery Juqun Xi,1 Jin Qin,2 Lei
23 Mei 2017 Poly-L-lysine Functionalized Large Pore Cubic Mesostructured Silica Nanoparticles as Biocompatible Carriers for Gene Delivery. Hartono
10 Aug 2016 A series of Ni incorporated Mesostructured Silica Nanoparticles (MSN) were prepared by physical mixing method.
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In order to address this issue, cell penetrating peptide (CPP) together with PEG modified and pore-enlarged mesostructured silica nanoparticle (NP) were constructed to form the mucus-penetrating electrostatic Core–shell nanoparticles consisting of iron oxide (α-Fe2O3) core and mesostructured silica–surfactant composite shell are treated with hexamethyldisiloxane under acidic conditions to achieve Mesostructured silica particles (∼100 nm diameter with ∼2 nm pores) prepared by surfactant-templated sol–gel techniques are versatile supports that can be easily derivatized with active molecules to create multifunctional materials. In this study, colloidal 30 nm HSNs were prepared by adding organically bridged alkoxysilane to an aqueous dispersion of mesostructured silica-surfactant composite nanoparticles, and the temporal changes of the morphology and chemical state of the nanoparticles were monitored to elucidate the formation mechanism. Synthesis and Characterization of Mesostructured Cellular Foam (MCF) Silica Loaded with Nickel Nanoparticles as a Novel Catalyst 54 . a graph known as an adsorption isotherm, whilst desorp- tion isotherm was obtained by measuring the quantities of nitrogen desorbed from the sample as the relative pressure was gradually lowered. Mesostructured silica-nanoparticle monolithic composites have been synthesized by dispersing prefabricated nanoparticles of gold or zeolite (silicalite) in ethanolic reaction mixtures containing SiCl4 and a Pluronic triblock copolymer template.
In this study, colloidal 30 nm HSNs were prepared by adding organically bridged alkoxysilane to an aqueous dispersion of mesostructured silica-surfactant composite nanoparticles, and the temporal changes of the morphology and chemical state of the nanoparticles were monitored to elucidate the formation mechanism. One of the major challenges in medicine is the delivery and control of drug release over time.
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Core–shell nanoparticles consisting of iron oxide (α-Fe2O3) core and mesostructured silica–surfactant composite shell are treated with hexamethyldisiloxane under acidic conditions to achieve
Herein, we took advantage of a BF 4 − anion hydrogen bonding strategy to anchor a chiral cationic rhodium/diamine complex within base‐functionalized mesostructured silica nanoparticles conveniently to construct a bifunctional heterogeneous catalyst. 2015-10-01 · Rose Bengal (RB), a xanthene dye, incorporated into mesostructured silica nanoparticles (MSNs) exhibits efficient singlet oxygen ((1)O2) generation when illuminated with 540 nm green light which is particularly promising for PDT applications. MESOSTRUCTURED SILICA NANOPARTICLES SUPPORTED ELECTROSYNTHESIZED GOETHITE IN CATIONIC SURFACTANT FOR PHOTODEGRADATION OF 2–CHLOROPHENOL . ROHAYU BINTI JUSOH .